Search results for "chiral [symmetry]"
showing 10 items of 134 documents
Infrared enhanced analytic coupling and chiral symmetry breaking in QCD
2005
We study the impact on chiral symmetry breaking of a recently developed model for the QCD analytic invariant charge. This charge contains no adjustable parameters, other than the QCD mass scale $\Lambda$, and embodies asymptotic freedom and infrared enhancement into a single expression. Its incorporation into the standard form of the quark gap equation gives rise to solutions for the dynamically generated mass that display a singular confining behaviour at the origin. Using the Pagels-Stokar method we relate the obtained solutions to the pion decay constant $f_{\pi}$, and estimate the scale parameter $\Lambda$, in the presence of four active quarks, to be about 880 MeV.
A Domino Ring‐Closure Followed by Retro‐Diels–Alder Reaction for the Preparation of Pyrimido[2,1‐ a ]isoindole Enantiomers
2016
A simple method was developed to prepare pyrimido[2,1-a]isoindole derivatives by using di-endo- and di-exo-ethyl 3-aminobicyclo[2.2.1]hept-5-ene-2-carboxylate enantiomers as chiral sources. The method is based on a domino ring-closure reaction of norbornene 2-aminohydroxamic acid followed by microwave-induced retro-Diels–Alder reaction. In the case of enantiomeric starting substances, the chirality is transferred from norbornene derivatives to pyrimido[2,1-a]isoindoles. The configurations of the synthesized compounds were determined by 1D and 2D NMR spectroscopy [based on 2D NOE cross-peaks and 3JH,H coupling constants] and X-ray crystallography.
Direct chromatographic study of the enantioselective biodegradation of ibuprofen and ketoprofen by an activated sludge
2018
[EN] The quantification of the enantiomeric fraction (EF) during the biodegradation process is essential for environmental risk assessment. In this paper the enantioselective biodegradation of ibuprofen, IBU, and ketoprofen, KET, two of the drugs most consumed, was evaluated. Biodegradation experiments were performed in batch mode using a minimal salts medium inoculated with an activated sludge (collected from a Valencian Waste Water Treatment Plant) and supplemented with the racemate of each compound. The inoculum activity was verified using fluoxetine as reference compound. The experimental conditions used (analyte concentration and volume of inoculum) were chosen according to OECD guidel…
Synthesis, photophysical properties and structures of organotin-Schiff bases utilizing aromatic amino acid from the chiral pool and evaluation of the…
2017
Abstract Five new organotin(IV) complexes of compositions [Me 2 SnL 1 ] ( 1 ), [Me 2 SnL 2 ] n ( 2 ), [Me 2 SnL 3 ] ( 3 ), [Ph 3 SnL 1 H] n ( 4 ) and [Ph 3 SnL 3 H] ( 5 ) (where L 1 = (2 S )-2-(( E )-(( Z )-4-hydroxypent-3-en-2-ylidene)amino)-3-(1 H -indol-3-yl)propanoate, L 2 = (2 S )-( E )-2-((2-hydroxybenzylidene)amino)-3-(1 H -indol-3-yl)propanoate and L 3 = (2 S )-( E )-2-((1-(2-hydroxyphenyl)ethylidene)amino)-3-(1 H -indol-3-yl)propanoate were synthesized and spectroscopically characterized. The crystal structures of 1 – 4 were determined. For the dimethyltin derivative 2 , a polymeric chain structure was observed as a result of a long Sn∙∙∙O contact involving the exocyclic carbony…
Calix[4]arene-Based Bis[2]catenanes: Synthesis and Chiral Resolution
2007
The exclusive formation of hydrogen-bonded dimers between tetraaryl and tetratosylurea calix[4]arenes has been used to prepare a series of ten "bisloop" tetraurea calix[4]arenes 3, in which adjacent phenylurea groups are covalently linked through alpha,omega-dioxyalkane chains. This dimerization with tetratosylurea 2 as template preorganizes the alkenyl residues of tetra(m-alkenyloxyphenyl) ureas 1 and enables their selective connection in high yield (up to 95 %) by olefin metathesis followed by hydrogenation. The "bisloop" calixarenes 3 also exclusively form heterodimers with 1. Thus, in a separated metathesis/hydrogenation sequence, a series of 14 cyclic bis[2]catenanes 4, in which two ca…
Diquark correlations in hadron physics: Origin, impact and evidence
2020
The last decade has seen a marked shift in how the internal structure of hadrons is understood. Modern experimental facilities, new theoretical techniques for the continuum bound-state problem and progress with lattice-regularised QCD have provided strong indications that soft quark+quark (diquark) correlations play a crucial role in hadron physics. For example, theory indicates that the appearance of such correlations is a necessary consequence of dynamical chiral symmetry breaking, viz. a corollary of emergent hadronic mass that is responsible for almost all visible mass in the universe; experiment has uncovered signals for such correlations in the flavour-separation of the proton's elect…
Generalized Polarizabilities and the Chiral Structure of the Nucleon
1997
We are studying the electron scattering process e p to e' p' gamma in order to obtain information on the genuine virtual Compton scattering (VCS) process gamma^* N to gamma N. In addition to the two kinematical variables of real Compton scattering, e.g. the scattering angle theta and the energy omega' of the outgoing photon, the invariant amplitude for VCS depends on a third kinematical variable, which we choose as the absolute value of the three-momentum transfer to the nucleon. The structure-dependent coefficients in the VCS amplitude therefore acquire a momentum dependence and are termed ``generalized polarizabilities'' of the nucleon in analogy to real Compton scattering. Utilizing the …
Meson Resonances at large Nc: Complex Poles vs Breit-Wigner Masses
2009
The rigorous quantum mechanical definition of a resonance requires determining the pole position in the second Riemann sheet of the analytically continued partial wave scattering amplitude in the complex Mandelstam s variable plane. For meson resonances we investigate the alternative Breit–Wigner (BW) definition within the large NC expansion. By assuming that the pole position is View the MathML source and exploiting unitarity, we show that the BW determination of the resonance mass differs from the pole position by View the MathML source terms, which can be extracted from ππ scattering data. For the case of the σ (f0(600)) pole, the BW scalar mass is predicted to occur at not, vert, simila…
Chiral Symmetry of Baryons
2001
We study chiral symmetry aspects of the positive and negative parity baryons by identifying them with linear representations of the chiral group $SU(N_{f}) \otimes SU(N_{f})$. It is shown that there are two distinctive schemes: naive and mirror assignments. We construct linear sigma models for baryons in the two assignments and examine their physical implications. Then we investigate properties of the naive and mirror nucleons microscopically by using QCD interpolating fields. Finally, we propose experiments to distinguish the two chiral assignments for the nucleon.
Three-body hadron systems with strangeness
2013
Recently, many efforts are being put in studying three-hadron systems made of mesons and baryons and interesting results are being found. In this talk, we summarize the main features of the formalism used to study such three hadron systems with strangeness S = -1, 0 within a framework built on the basis of unitary chiral theories and solution of the Faddeev equations. In particular, we present the results obtained for the pi(K) over barN, K (K) over barN and KK (K) over bar systems and their respective coupled channels. In the first case, we find four Sigma's and two A's with spin-parity J(P) = 1/2(+), in the 1500-1800 MeV region, as two meson-one baryon s-wave resonances. In the second cas…